Colour Picker is a program with a simple interface which will allow you to pick a colour using the normal windows colour picker.
You can also select any picture and grab a colour from it. Enter RGB values or Hex value to get a colour .It will then convert these colours to a VB hex value, RGB value, HTML value. You can then copy any colour format to the clipboard.You can also adjust the RGB slide controls and see in realtime the effect.
There is an option to save a scheme of colours to file. This program would be helpful in designing VB projects or Web sites.